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Tincture of iodine (antiseptic): add 70 g of iodine and 50 g of KI to 50 mL of water; make up to one liter with alcohol o-Tolidine solution (for residual chlorine in water analysis): dissolve 1 g of pulverized otolidine, mp 129 C, in one liter of dilute hydrochloric acid (100 mL conc HCl diluted to one liter) Toluylene red (indicator): see neutral red Trichloroacetic acid: dissolve 100 g of the acid in water and dilute to one liter Trinitrobenzene, 1,3,5-trinitrobenzene (indicator): dissolve 01 g in 100 mL alcohol; pH range colorless 115 140 orange Trinitrobenzoic acid, 2,4,6-trinitrobenzoic acid (indicator): dissolve 01 g in 100 mL water; pH range colorless 120 134 orange-red Tropeolin D (indicator): see methyl orange Tropeolin O, sodium 2,4-dihydroxyazobenzene-4-sulfonate (indicator): dissolve 01 g in 100 mL water; pH range yellow 110 130 orange-brown Tropeolin OO, orange IV, sodium p-diphenylamino-azobenzene sulfonate, sodium 4 anilino-azobenzene-4-sulfonate (indicator): dissolve 01 g in 100 mL water; pH range red 13 32 yellow Tropeolin OOO, sodium -naphtholazobenzene sulfonate (indicator): dissolve 01 g in 100 mL water; pH range yellow 76 89 red Turmeric paper (gives a rose-brown coloration with boric acid); wash the ground root of turmeric with water and discard the washings Digest with alcohol and lter, using the clear ltrate to impregnate white, unsized paper, which is then dried Uffelmann s reagent (gives a yellow coloration in the presence of lactic acid): add a ferric chloride solution to a 2% phenol solution until the solution becomes violet in color Wagner s solution (phosphate rock analysis): dissolve 25 g citric acid and 1 g salicylic acid in water, and make up to one liter Twenty- ve to 50 mL of this reagent prevents precipitation of iron and aluminum Wijs solution (for iodine number): dissolve 13 g resublimed iodine in one liter of glacial acetic acid (995%), and pass in washed and dried (over or through H2SO4) chlorine gas until the original thio titration of the solution is not quite doubled There should be only a slight excess of iodine and no excess of chlorine Preserve the solution in amber colored bottles sealed with paraf n Do not use the solution after it has been prepared for more than 30 days Xylene cyanole-methyl orange indicator, Schoep e modi cation (for partially color blind operators): dissolve 075 g xylene cyanole FF (Eastman No T 1579) and 150 g methyl orange in 1 liter of water p-Xylenol blue, 1,4-dimethyl-5-hydroxybenzene-sulfonphthalein (indicator): dissolve 01 g in 250 mL alcohol; pH range (acid) red 12 28 yellow, and (alkaline) yellow 80 96 blue Zinc chloride, ZnCl2 05N: 34 g per liter Zinc nitrate, Zn(NO3)2 6H2O 05N: 74 g per liter Zinc sulfate, ZnSO4 7H2O 05N: 72 g per liter.

26 26 27 25, 28 30 30

ipate in the reaction The ratios obtained from the numerical coef cients in the chemical equation are the stoichiometric ratios that permit one to calculate the moles of one substance as related to the moles of another substance in the chemical equation For example, the stoichiometric equation for the combustion of heptane C7H16 11O2 7CO2 8H2O

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indicates that 1 mol (not kilogram) of heptane will react with 11 mol of oxygen to give 7 mol of carbon dioxide plus 8 mol of water These may be pound-moles, kilogram-moles, gram-moles or any other type of mole, as shown in Fig 42 One mol of CO2 is formed from each 1 7 mol of C7H16 Also, 1 mol of H2O is formed with each 7 8 mol of CO2 Thus the equations tell us in terms of moles (not kilograms) the ratios among reactants and products

10, 29 10, 29 29 9 9 30 30 30

Example 41 Determine the mass of oxygen that can be produced by the complete decomposition of 490 g of potassium chlorate

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